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Wednesday, 30 November 2016
Problem set 33
The radius of the Fermi sphere of free electrons in a monovalent metal with an fcc
structure, in which the volume of the unit cell is a^3, is
\left(\frac{12\pi^2}{a^3}\right)^{1/3}
\left(\frac{3\pi^2}{a^3}\right)^{1/3}
\left(\frac{\pi^2}{a^3}\right)^{1/3}
\left(\frac{1}{a}\right)^{1/3}
The radius of Fermi sphere is given by k_f=\left(\frac{3\pi^2N}{V}\right)^{1/3}. For FCC structure \frac{N}{V}=\frac{4}{a^3}.
Hence, k_f\left(\frac{12\pi^2}{a^3}\right)^{1/3}. Hence, answer is (A).
Deviation from Rutherford scattering formula for \alpha-particle scattering gives an estimate of:
Size of an atom
Thickness of target
Size of a nucleus
half life of \alpha-emitter
Rutherford formula is derived by assuming nucleus to be point charge. However, nucleus is not a point charge. However, nucleus
is not a point charge. There is a charge distribution inside the nucleus. Due to which there is change in angular dependence
of scattering. From this information one can estimate size of nucleus.
Hence, answer is (C)
If the critical magnetic field for aluminium is 7.9\times 10^3 A/m, the critical current which can flow through long thin superconducting wire of aluminium of diameter 1\times10^{-3}m is
5.1 A
1.6 A
4.0 A
2.48 A
Critical current is given by
\begin{align*}
I_c&=2\pi rH_c\\
&=2\times3.14*0.5\times10^{-3}\times7.9\times 10^3\\
&=2.48 A
\end{align*}
Hence, answer is (D)
An elemental dielectric has a dielectric constant \epsilon=12 and it contains 5\times10^{18} atoms/m^3. Its electronic
polarizability in uints of FM^2 is
4.17\times10^{-30}
8.34\times10^{-30}
6.32\times10^{-30}
12.64\times10^{-30}
The Clausius Mossotti relation is
\frac{\epsilon_r-1}{\epsilon_r+2}=\frac{N\alpha_e}{3\epsilon_0}\begin{align*}
\alpha_e&=\frac{\epsilon_r-1}{\epsilon_r+2}\frac{3\epsilon_0}{N}\\
&=\frac{12-1}{12+2}\frac{3\times8.85\times10^{-12Fm^{-1}}}{5\times10^{18} atoms/m^3}\\
&=4.17\times10^{-30}FM^2\\
\end{align*}
Hence, answer is (A)
Mangetite (Fe_3O_4) has a cubic structure with a lattice constant of 8.4A^o. The saturation magnetization in this
material in units of A/m is :
6.2\times10^5
6.2\times10^6
12.4\times10^6
12.4\times10^5
As each O has an oxidation number of -2 and there are 4 of them in the formula,
the 3 Fe atoms must together have a charge of +8. This is consistent with their
being two Fe^{3+} ions and one Fe^{2+} per formula unit. The ratio of Fe^{3+} ions to Fe^{2+} is 2 to 1.
There are 8 Fe_3O_4 units per unit cell. Hence, there are 24 Fe atoms in unit cell, out of which 16 are Fe^{3+} and 8
are Fe^{2+}. Out of the 16 Fe^{3+} ions 8 Fe^{3+} ions are at octahedral position and 8 Fe^{3+} ions are
at tetrahedral position. The ions in tetrahedral sites oppose the applied magnetic field and the ions at octahedral positions
reinforce the field. Consequently, Fe^{3+} ions neutralizes the Fe^{3+} at octahedral positions.
In each Fe^{3+} there are 5 unpaired 3d electrons and in each Fe^{2+} there are 4 unpaired 3d electrons.
Each unpaired electron has magnetic moment one Bohr magneton \mu_B=9.27\times10^{-24}Am^2. Hence, each Fe^{2+} ion has
4\mu_B magnetic moment. As, unit cell contains 8 Fe^{2+} ions, total magnetic moment is 32\mu_B.
Hence, saturation magnetization
\begin{align*}
M&=\frac{32\mu_B}{a^3}\\
&=\frac{32\times9.27\times10^{-24}}{\left(8.4\times10^{-10}\right)^3}\\
&=5.1\times10^5A/m
\end{align*}
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